Four CoII-GdIII mixed-metal phosphonate clusters as molecular magnetic refrigerants
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چکیده
منابع مشابه
Phosphonate-substituted zirconium oxo clusters
ABSTRACT The phosphonate-substituted zirconium oxo clusters Zr6O2(OBu)12(O3PPh)4 and Zr7O2(OiPr)12(O3PCH2CH2CH2Br)6, with octahedrally coordinated Zr atoms, were synthesized by reaction of zirconium alkoxides with phosphonic acid bis(trimethylsilyl) esters. The basic structural motif are Zr3O(µ2-OR)3(OR)3 units which are connected in different ways. GRAPHICAL ABSTRACT
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The reaction of VCl(3) with 3,5-dimethylpyrazole (3,5-Me(2)PzH) and trichloromethylphosphonic/tert-butylphosphonic acid in the presence of triethylamine as a hydrogen chloride scavenger afforded the tetranuclear V(IV) assemblies, [(VO)(4)(3,5-Me(2)PzH)(8)(CCl(3)PO(3))(4)] (1) and [(VO)(4)(3,5-Me(2)PzH)(4)(t-BuPO(3))(4)] (2). Both of these compounds possess a distorted cubic framework structures...
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Mixed-valent manganese phosphonate clusters [Mn(II)(8)Mn(III)(2)O(2)(O(3)PC(10)H(7))(4)(C(6)H(5)CO(2))(10)(py)(4)(H(2)O)(2)] (1) and [Mn(II)(4)Mn(III)(9)O(4)(OH)(2)(O(3)PC(10)H(7))(10)(C(6)H(5)CO(2))(5)(py)(8)(H(2)O)(6)] (2) are reported. Compound 1 is the first example of manganese phosphonate clusters prepared through a microwave-assisted technique. While compound 2 is obtained under ambient ...
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Yuji Yoshida shigeo suzuki Yuji Mukai Kazuo Nakatani Katsuhiko Fujiwara* Matsushita Electric Industrial Co., Ltd. Central Research Laboratory 3 15 Yagumo-Nakamachi Moriguchi, Osaka 570, JAPAN *Air-conditioner Division The use of mixed refrigerants for heat-pump cycles h ave attracted the attention of the International Energy Agency as an important subject of heat-pump technology and its re sear...
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ژورنال
عنوان ژورنال: Inorganica Chimica Acta
سال: 2016
ISSN: 0020-1693
DOI: 10.1016/j.ica.2016.08.021